Dehydrocoupling routes to element–element bonds catalysed by main group compounds
نویسندگان
چکیده
منابع مشابه
Yttrium-catalysed dehydrocoupling of alanes with amines.
We report [Y{N(SiMe3)2}3] as a precatalyst for the dehydrocoupling of sterically demanding amines with β-diketiminate stabilised aluminium dihydrides. While simple fluorinated anilines readily undergo Al-H/N-H dehydrocoupling under thermal conditions, catalytic methods are required to achieve reasonable rates of reaction for ortho-substituted anilines or hindered aliphatic amines.
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A systematic approach to the deuteriation of polypyridyl type ligands is reported. A range of isotopologues of heteroaromatic compounds containing pyrazyl, pyridyl, 1,2,4-triazole, thienyl, methyl, and phenyl moieties, have been prepared in a cost-effective manner, using a range of methods based on subcritical aqueous media. Selectively and fully deuteriated ligands are characterized by mass sp...
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ژورنال
عنوان ژورنال: Chemical Society Reviews
سال: 2016
ISSN: 0306-0012,1460-4744
DOI: 10.1039/c5cs00521c